期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 15, 页码 5989-5992出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo800700b
关键词
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The Duff reaction (HMTA, AcOH or TFA) was studied on substituted [6 + 5] heterocyclic compounds. This reaction provides a useful route to aldehydes for Compounds bearing sensitive amide functions. It gives also access to tricyclic lactams of potential biological interest. The formation of an aminomethyl intermediate in the Duff reaction mechanism is unequivocally demonstrated.
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