期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 21, 页码 8422-8436出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8015852
关键词
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资金
- Fonds der Chernischen Industrie
- SFB 749
- DFG
A wide range of polyfunctional aryl, heteroaryl, alkyl, and benzylic zinc reagents were coupled with unsaturated aryl halides bearing an acidic NH or OH proton, using Pd(OAc)(2) (1 mol %) and S-Phos (2 mol %) as catalyst without the need of protecting groups. A similar nickel-catalyzed reaction is described. The relative kinetic basicity of orcyanozinc compounds as well as their stability toward acidic protons is also described.
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