期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 9, 页码 3593-3595出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8002453
关键词
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Crystallization-induced secondary selection from a tandem driven dynamic combinatorial library is presented. In a one-pot experiment, an initial nitroaldol equilibrium was kinetically driven by a tandem reaction resulting in a subsequent dynamic library of diastereoisomers. This library was then further driven by a phase change, resulting in amplification and isolation of a highly diastereomerically enriched and synthetically interesting isoindolinone.
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