期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 4, 页码 1605-1607出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo7021197
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资金
- NIGMS NIH HHS [GM060287] Funding Source: Medline
[GRAPHICS] The conversion of 2-butyn-1,4-diol to (Z)-2,4-diiodobut-2-en-1-ol proceeded efficiently using in situ generated trimethylsilyl iodide. Coupling with Grignard reagents and other nucleophiles delivered (2Z)-2-iodo allylic alcohols. The geometry of the products was established by nOe.
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