期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 3, 页码 1031-1035出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo702250z
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资金
- NIGMS NIH HHS [GM038436] Funding Source: Medline
[GRAPHICS] A synthesis of the C(1)-C(11) fragment of apoptolidin A has been accomplished by a convergent route involving the stereoselective glycosidation of 9 and the Suzuki cross-coupling reaction of bromodienoate 7 and the vinylborane generated via chemoselective hydroboration of diyne 6 with diisopinocampheylborane.
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