期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 15, 页码 6014-6017出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo8009837
关键词
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Small libraries of di-, tri-, and tetragalactosyl clusters were efficiently synthesized using combinatorial methodology, on solid support, by click chemistry assisted by microwaves, starting from different poly alkyne DNA-based scaffolds and two galactosyl azide derivatives. The scaffold was synthesized by standard DNA solid-supported phosphoramidite chemistry using a novel alkyne phosphoramidite and an alkyne solid support. The proportion of each glycocluster in a library was modulated using different molar ratios of both galactose azides.
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