期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 73, 期 22, 页码 9144-9147出版社
AMER CHEMICAL SOC
DOI: 10.1021/jo801762b
关键词
-
资金
- Council for Scientific and Industrial Research (CSIR), New Delhi [01(2225)/08/EMR-II]
A new C-3-symmetric drum-shaped homoditopic haxaamino bicyclic cyclophane and its hexachloride and hexaiodide complexes have been synthesized and characterized and dual recognition of guests has been demonstrated. Single-crystal X-ray analysis illustrates that bicyclic cyclophane has a cavity and side pockets for acetone molecules. The hexaprotonated state of this bicycle shows encapsulation of an iodide inside its cavity, and in hexachloride complex, chloride is recognized as Cl-center dot center dot center dot H2O in each of the three side pockets which are in extensive hydrogen bonding interactions with the water and chlorides. H-1 NMR experiments have also been carried out on hexatosylated cyclophane with the halides to study solution state binding.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据