期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 17, 期 8, 页码 5670-5678出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp04942j
关键词
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资金
- Office of Science (BES), U.S. Department of Energy [DE-FG02-08ER64529]
- National Science Foundation [1249565, 0959452]
- NASA Earth and Space Science Fellowship Program
- Japan Society for the Promotion of Science Fellowship for Research Abroad
- Directorate For Geosciences [1249565] Funding Source: National Science Foundation
The production of secondary organic material (SOM) by the reactive uptake of isoprene photooxidation products was investigated using partially to wholly neutralized sulfuric acid particles. The experiments were performed at a relative humidity (RH) of <5% and a temperature of 20 degrees C. The extent X of neutralization was adjusted from that of sulfuric acid (X = 0) to that of ammonium sulfate (X = 1). Significant SOM production was observed only for X < 0.7. The threshold of 0.7 corresponded to the transition point of the sulfate particles from aqueous to solid for <5% RH. The phase transition of inorganic sulfate therefore regulated the particle-phase reactions that produce isoprene SOM, at least for the investigated conditions. For aqueous particles, a decreasing extent of neutralization was associated with increasing production of SOM, including increased production of oligomers and organosulfates. These results can underpin treatments of phase-dependent SOM production within chemical transport models, thereby improving the accuracy of simulations of biogenic-anthropogenic interactions in the atmosphere and the associated impacts of aerosol particles on climate and air quality.
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