4.6 Article

A slow, continuous beam of cold benzonitrile

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PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 17, 期 7, 页码 5372-5375

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cp03818e

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  1. Direct For Mathematical & Physical Scien
  2. Division Of Physics [1125846] Funding Source: National Science Foundation

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A cold, continuous, high flux beam of benzonitrile has been created via buffer gas cooling. The beam has a typical forward velocity of 67 +/- 5 m s(-1), a velocity spread of +/- 30 m s(-1) and a typical flux of 10(15) molecules s(-1), measured via microwave spectroscopy. This beam represents the slowest demonstrated forward velocity for any cold beam of medium sized (>5 atoms) polyatomic molecules produced to date, demonstrating a new source for high resolution spectroscopy. The expected resolution of a spectrometer based on such beams exceeds current instrument-limited resolution by almost an order of magnitude. This source also provides an attractive starting point for further spatial manipulation of such molecules, including eventual trapping.

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