期刊
JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 357, 期 19-20, 页码 3435-3441出版社
ELSEVIER
DOI: 10.1016/j.jnoncrysol.2011.06.014
关键词
Silica aerogel; CVD; Polysilsesquioxane; Mechanical properties; Sol-gel
资金
- United States Department of Energy [W-7405-ENG-36]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [840336] Funding Source: National Science Foundation
Low-density monolithic silica and hexylene-bridged polysilsesquioxane aerogels were chemical vapor deposition (CVD) treated with hexamethyldisilazane or hexachlorodisilane silylating agents producing TMS (trimethylsilane) or Si layers on the aerogel. Reinforcing the weak aerogels by controlled deposition process improved their compressive strength and preserved their properties characteristic of low-density aerogels. When the silica and hexylene-bridged polysilsesquioxane aerogels were CVD treated with hexamethyldisilazane, the compressive modulus more than doubled in some cases. However, when treating hexylene-bridged aerogels with hexachlorodisilane the compressive modulus increased six fold. Not only did CVD treatment of the aerogels improve the compressive modulus, but the low densities, high surface areas, high porosities, and the transparency of the aerogels were not significantly affected. Published by Elsevier B.V.
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