期刊
JOURNAL OF NON-CRYSTALLINE SOLIDS
卷 356, 期 28-30, 页码 1416-1424出版社
ELSEVIER
DOI: 10.1016/j.jnoncrysol.2010.05.005
关键词
Amorphous metal; Crystal nucleation; Nanocrystals; Transmission electron microscopy
资金
- United States Department of Energy (USDOE), Office of Science (OS), Office of Basic Energy Science (BES), under Ames Laboratory [DE-AC02-07CH11358]
- US Department of Energy, Office of Science, Basic Energy Sciences [DE-AC02-06CH11357]
The transformation kinetics and microstructural evolution during initial crystallization in highly driven Al90Sm10 were investigated using transmission electron microscopy (TEM). conventional Cu K-alpha and high-energy synchrotron X-ray diffraction (HEXRD) and differential scanning calorimetry (DSC). The highest cooling rate obtained in this study yielded a high number density of fcc-Al nanocrystals, with sizes on the order of 2-5 nm, embedded in a disordered matrix rich in an Al-Sm medium range order (MRO) structure. Isothermal in-situ HEXRD results indicated a single crystallization of a large primitive cubic phase from the disordered state. Further analysis using DSC showed two crystallization events; a small peak overlapping the peak from the main crystallization event. TEM analysis performed at different stages of crystallization resolved pre-existing fcc-Al crystals, further crystallization of fcc-Al, (corresponding to the first small peak) and evolution of the cubic phase, corresponding to the main crystallization event. Fcc-Al nanocrystals showed a restricted growth and stayed at an average size of 16 nm after full crystallization was established. Transformation kinetics was described using Johnson-Mehl-Avrami approach after deconvolution of the overlapping crystallization peaks using a Gaussian approximation. (C) 2010 Elsevier B.V. All rights reserved.
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