Structural study of sol-gel silicate glasses by IR and Raman spectroscopies

A study of the Structure and bonding configuration of sol-gel silicate glasses by Raman and infrared spectroscopies is presented. Moreover, a review of the Raman lines and infrared bands assignment, the identification of the non-bridging silicon-oxygen groups and the ring structures are also demonstrated. The evolution of the changes of the bonding configuration in the composition and the stabilization temperature of the bioactive glasses is discussed in terms of the structural and textural characteristics of the glasses. Raman and infrared analyses contribute to the improvement in understanding of the local symmetry for sol-gel silicate glasses. infrared spectroscopy has allowed to identify the vibration bands of the hydroxyl groups associated with various configurations of the terminal silanol bonds on the glass surface and the free molecular water in the glass matrix. Raman analysis has provided an alternative method of quantifying the network connectivity grade and predicting the textural properties of the sol-gel silicate glasses. (C) 2009 Elsevier B.V. All rights reserved.