期刊
PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES
卷 14, 期 6, 页码 1138-1146出版社
SPRINGERNATURE
DOI: 10.1039/c5pp00080g
关键词
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资金
- Danish National Research Foundation
- EU Marie Curie Training Program [TopBio PITN-GA-2010-264362]
- Foundation for Polish Science [TEAM-2009-4/3]
The photophysical properties of two indoline-based octupolar merocyanine dyes and of the corresponding quinoline-based dyes were examined. This seemingly subtle structural change in the chromophore of these molecules has an appreciable effect on the yields with which these respective compounds sensitize the production of singlet molecular oxygen, O-2(a(1)Delta(g)). The indoline-based dyes are reasonably efficient O-2(a(1)Delta(g)) sensitizers (phi(Delta) similar to 0.35), whereas the quinoline-based dyes are poor O-2(a(1)Delta(g)) sensitizers (phi(Delta) similar to 0.005). A series of experiments, including Laser-Induced Optoacoustic Calorimetric (LIOAC) measurements, reveal that this difference principally reflects the fact that the excited singlet state of the quinoline-based dyes rapidly and efficiently decays via nonradiative channels to regenerate the ground state molecule. It is likely that a charge-transfer state mediates this efficient coupling between the excited and ground states. Such subtle, structure-dependent effects are important in elucidating and ultimately understanding phenomena that influence the efficiency of photosensitized O-2(a(1)Delta(g)) production. In turn, the knowledge gained facilitates the rational design and preparation of O-2(a(1)Delta g) sensitizers with explicitly controlled properties.
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