期刊
JOURNAL OF NATURAL PRODUCTS
卷 71, 期 8, 页码 1475-1478出版社
AMER CHEMICAL SOC
DOI: 10.1021/np800230d
关键词
-
资金
- NSF [CHE-0617056, CHE-0342912, REU 0552641]
- NIH [R01 CA 047135, S 10 RR 19918, S10 RR20939, NIGMS R25GM058903]
The dramatic biogeographical variations in the secondary metabolites from Psammocinia aff. bulbosa have complicated our efforts to reisolate the two most cytotoxic of its metabolites, (+)-psymberin and (+)-cyclocinamide A. Reported now are the results of a new study that demonstrates our ability to repeatedly isolate these two compounds through targeted collection efforts. Additional study of the new sample of (+)-cyclocinamide A has enabled finalizing its biological activity and absolute stereochemistry as 4S. 7S, 11S, 14S.
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