期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 14, 期 7, 页码 5370-5374出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2014.8069
关键词
Fullerene; Corrole; Dyad; Electron Transfer
类别
资金
- National Basic Research Program of China (973 Program) [2012CB932601, 2009CB930204]
- National Natural Science Foundation of China [21271174, 20971124]
A new electron transfer dyad, covalently linked C-70-corrole, was prepared via C-70 and 10-(4-Formylaryl)-5,15-bis(pentafluorophenyl). The structures and the properties of the new material were investigated by HPLC, MALDI-TOF-MS, UV-Vis-NIR spectroscopy, NMR, fluorescence analysis and CV/DPV. The free-energy of C-70-corrole calculated by employing the redox potentials and singlet excited-state energy suggested the possibility of electron transfer from the excited singlet state of corrole to the fullerene entity, which agreed with the results of the theoretical calculation.
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