期刊
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
卷 13, 期 4, 页码 2624-2631出版社
AMER SCIENTIFIC PUBLISHERS
DOI: 10.1166/jnn.2013.7375
关键词
Diesel Engine Exhaust; Perovskite Oxide; Soot; NOx; Mechanism
类别
资金
- National Natural Science Foundation of China [50134020]
- Jiangsu Province's Postgraduate Cultivation and Innovation Project [CX10B-257Z]
The nanocrystalline, porous, perovskite La0.8K0.2Fe1-xMnxO3 (x = 0-0.5) catalysts were prepared by the citrate-gel process. All the perovskite catalysts can effectively catalyze the soot combustion and among them the La0.8K0.2Fe0.7Mn0.3O3 catalyst exhibits the highest catalytic activity, with a lowest T-50 (366 degrees C). This optimized La0.8K0.2Fe0.7Mn0.3O3 catalyst then was coated onto a honeycomb ceramic by the citrate-gel assisted dip-coating method and its catalytic performance was evaluated by the bench test in the practical exhaust emission. It is proved that the La0.8K0.2Fe0.7Mn0.3O3-coated honeycomb ceramic device simultaneously has a effective capture of soot particulates and a good absorption of NOx from the exhaust emission at a low temperature and begins to efficiently catalyze oxidization reactions of the soot particulates at around 230 degrees C, and conversion of NOx at about 290 degrees C, with a conversion rate of 16.6% at 400 degrees C. This catalytic performance enhancement for simultaneous removal of soot and NOx can be largely attributed to the synergistic effect of Fe and Mn, pore structure of a large channel with various small pores connected, and microstructural characteristics of La0.8K0.2Fe0.7Mn0.3O3 catalyst. The catalytic mechanism of capture-oxidation-reduction is rationally proposed.
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