Synthesis of Flower-Like CuS Nanostructured Microspheres Using Poly(ethylene glycol) 200 as Solvent

CuS flower-like microspheres with the diameter of about 3 similar to 4 mu m constructed by nanoflakes with thickness of about 30 similar to 40 nm have been successfully synthesized by a simple wet chemical method. In this reaction system, Poly(ethylene glycol) 200 (PEG 200) was used as solvent, CuCl2 center dot 2H(2)O as cuprum source, and thioacetamide (TAA) as sulfur source. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and high-resolution transmission electron microscopy (HRTEM) in detail. The XRD patterns revealed that the products were pure hexagonal phase of CuS. Experiments with various parameters indicated that the reaction temperature and molar ratio of CuCl2 center dot 2H(2)O to thioacetamide had strong effects on the sizes and morphologies of CuS crystals. A possible growth mechanism on the formation of CuS microspheres was proposed. The PEG 200 acted as solvent, complexing agent, and soft template in this synthesis. Furthermore, optical studies of the products including UV Vis absorption spectrum and photoluminescence spectrum have also been carried out.