期刊
JOURNAL OF NANOPARTICLE RESEARCH
卷 16, 期 7, 页码 -出版社
SPRINGER
DOI: 10.1007/s11051-014-2474-3
关键词
Graphene; Reduced graphene oxide; Nanocrystalline cellulose; Click reaction
资金
- University of Tabriz
- Research Center for Pharmaceutical Nanotechnology (RCPN)
Reduced graphene oxide (RGO) sheet was functionalized with nanocrystalline cellulose (NCC) via click coupling between azide-functionalized graphene oxide (GO-N-3) and terminal propargylfunctionalized nanocrystalline cellulose (PG-NCC). First, the reactive azide groups were introduced on the surface of GO with azidation of 2-chloroethyl isocyanate-treated graphene oxide (GO-Cl). Then, the resulted compounds were reacted with PG-NCC utilizing copper-catalyzed azide-alkyne cycloaddition. During the click reaction, GO was simultaneously reduced to graphene. The coupling was confirmed by Fourier transform infrared, Raman, DEPT135, and C-13 NMR spectroscopy, and the complete exfoliation of graphene in the NCC matrix was confirmed with X-ray diffraction measurement. The degree of functionalization from the gradual mass loss of RGO-NCC suggests that around 23 mass % has been functionalized covalently. The size of both NCC and GO was found to be in nanometric range, which decreased after click reaction.
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