期刊
JOURNAL OF NANOMATERIALS
卷 2011, 期 -, 页码 -出版社
HINDAWI LTD
DOI: 10.1155/2011/292516
关键词
-
资金
- GACR [304/07/1129]
- [1M0554]
A simple and effective method for the fabrication of porous nanofibers based on the solvent evaporation methods in one-step electrospinning process from the commercial polyvinyl butyral (PVB) is presented. The obtained nanofibers are prevalently amorphous with diameters ranging from 150 to 4350 nm and specific surface area of approximately 2-20 m(2)/g. Pore size with irregular shape of the porous PVB fibers ranged approximately from 50 to 200 nm. The effects of polymer solution concentration, composition of the solvents mixture, and applied voltage on fiber diameter and morphology were investigated. The theoretical approach for the choice of poor and good solvents for PVB was explained by the application Hansen solubility parameter (HSP) and two-dimensional graph. Three basic conditions for the production of porous PVB nanofibers were defined: (i) application of good/poor solvent mixture for spinning solution, (ii) differences of the evaporation rate between good/poor solvent, and (iii) correct ratios of good/poor solvent (v/v). The diameter of prepared porous PVB fibers decreased as the polymer concentration was lowered and with higher applied voltage. These nanofiber sheets with porous PVB fibers could be a good candidate for high-efficiency filter materials in comparison to smooth fibers without pores.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据