期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 1074, 期 -, 页码 687-694出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2014.05.004
关键词
Porphyrin; Naphthalimide; Metal complex; Light harvesting
资金
- National Basic Research Program of China (973 Program) [2009CB930601]
- Ministry of Education of China [IRT1148]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1148]
- National Natural Science Foundation of China [BZ2010043, 20974046, 20774043, 51173081, 50428303, 611360 03, 50803027]
- Natural Science Foundation of Jiangsu Province [BK2008053, BK2009025, 10KJB510013]
- Research Fund for Nanjing University of Posts and Telecommunications, China [NY213176]
A novel porphyrin naphthalimide pentamer 5 was synthesized by linking four light-harvesting naphthalimide units to a central porphyrin, via ether bridges. The corresponding metal (Zn2+, Cu2+, Mn2+, Fe3+, Co2+) complexes 6a-6e were obtained under different reaction conditions. The structures of these compounds were characterized by H-1 and C-13 NMR spectra, FT-IR, MALDI-TOF-MS and elemental analysis. The photophysical properties have been investigated by UV-Vis absorption and steady-state fluorescence spectroscopy. It is found that the excitation energy transfer occurs from the naphthalimide units to the porphyrin core, and that the free base porphyrin 5 and Zn porphyrin 6a can emit intense red light. Additionally, the electrochemical properties of compounds 5 and 6a-6e were also investigated by cyclic voltammetry. (C) 2014 Published by Elsevier B.V.
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