Spectrophotometric and spectroscopic studies of charge transfer complex of 1-Naphthylamine as an electron donor with picric acid as an electron acceptor in different polar solvents

The charge transfer complex of 1-Naphthylamine as a donor with it-acceptor picric acid has been studied spectrophotometrically in different solvents at room temperature. The results indicate that the formation of charge transfer complex is high in less polar solvent. The stoichiometry of the complex was found to be 1:1 by straight line method. The data are analysed in terms of formation constant (K-CT), molar extinction coefficient (epsilon(CT)), standard free energy (Delta G degrees), oscillator strength (f). transition dipole moment (mu(EN)), resonance energy (R-N) and ionization potential (I-D). It is concluded that the formation constant (K-CT) of the complex is found to be depends upon the nature of both electron acceptor and donor and also on the polarity of solvents. Further the charge transfer molecular complex between picric acid and 1-Naphthylamine is stabilized by hydrogen bonding. (C) 2010 Elsevier B.V. All rights reserved.