期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 981, 期 1-3, 页码 111-119出版社
ELSEVIER
DOI: 10.1016/j.molstruc.2010.07.038
关键词
Elemental analysis; Humic acids; Scanning electron microscopy; Spectroscopy; Subtropical microbasin
资金
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) [BEX 4144/09-0]
Humic substances (HS) perform a fundamental role in aquatic environments, exhibiting different levels of reactivity in retaining metal ions and organic pollutants Also, they control the primary production of these ecosystems and act in the carbon sequestering process. In order to improve our understanding vis-a-vis the structural and functional features of HS from aquatic systems, this study aimed to chemically and spectroscopically characterize humic acids (HA) isolated from bottom sediment samples of a stream in a Brazilian subtropical microbasin by elemental analysis, and infrared (FT-IR), ultraviolet and visible (UV-Vis) and solid-state C-13 nuclear magnetic resonance (CP-MAS C-13 NMR) spectroscopies, thermogravimetry (TG), and scanning electron microscopy (SEM) Although all samples originated from the same environment, the data showed that the HA have distinct chemical and spectroscopic properties, and that the location and characteristics of the sampling points from which the sediments were collected played an important role in the differences observed Furthermore, vascular plant matter is probably the main contributor to these samples (C) 2010 Elsevier B.V. All rights reserved
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