期刊
JOURNAL OF MOLECULAR STRUCTURE
卷 931, 期 1-3, 页码 20-24出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molstruc.2009.05.021
关键词
Acylhydrazone; Pyrazine; Complexes; Amplitude; CH center dot center dot center dot O hydrogen bond
资金
- CNRS [UMR 7006]
The crystallographic structural features of the ditopic ligand pyrazine-2,5-dicarbaldehyde-bis(propionyl-N-methylhydrazone) 1, as well as their comparison with related ligands are herein reported. CH center dot center dot center dot O short contacts (2.46 and 2.55 angstrom) supporting network formation were observed. The amplitude of the conformational switch induced by the formation of the dinuclear rack-like complex [Cu(2)1(terpy)(2)](CF3SO3)(4) of ligand 1 (synthesized by reaction of 2,5-pyrazine-dicarboxaldehyde with two equivalents of N-methyl-propionohydrazide), has been determined on the basis of the X-ray structures and it was found to be of 3 angstrom. Moreover, the correlation between the structural data and the data obtained by 2D NMR spectroscopy, is confirmed by the mean of the structural analysis herein discussed that concerns the protons involved in the NOE effects observed by NOESY spectroscopy. (C) 2009 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据