期刊
JOURNAL OF MOLECULAR RECOGNITION
卷 27, 期 3, 页码 151-159出版社
WILEY
DOI: 10.1002/jmr.2343
关键词
chromogenic sensor; schiff base; cation recognition; aqueous medium; DFT; living cells
资金
- DRDO [ERIP/ER/1006004/M/01/1333]
Thiophene-based diimine (R1) and monoimine (R2) were synthesized in a single step, and their cation binding affinity was tested using colorimetric and UV-vis spectral studies. R1 selectively shows a colorimetric turn-on response for Pb2+, Hg2+ ions and colorimetric turn-off with Sn2+ ions, and R2 shows visual response for Cu2+ and Hg2+ over other examined metal ions in aqueous medium. R1 forms 1:1 complex with Pb2+, Hg2+, and Sn2+ and exhibits fluorescence quenching, whereas R2 shows 2:1 complex with Hg2+, Cu2+ and shows fluorescence enhancement. The structural and electronic properties of the sensors and their metal complexes were also investigated using Density Functional Theory calculations. R2 was also successfully demonstrated as a fluorescent probe for detecting Cu2+ ions in living cells. Copyright (c) 2014 John Wiley & Sons, Ltd.
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