期刊
JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC
卷 55, 期 3-4, 页码 126-129出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcatb.2008.02.009
关键词
Alcohol dehydrogenases; Anti-Prelog; Stereoselective reduction; alpha-Azido ketones; alpha-Nitro ketones; Biotransformation
资金
- CIBA SC (Basel)
- TIC
- FFG
- Province of Styria
Lyophilized cells of the open accessible bacterium Comamonas testosteroni DSM 1455 Proved to be an excellent catalyst for the asymmetric reduction of different alpha-azido, alpha-bromo, and alpha-nitro ketones at elevated substrate concentrations (16 g/L) in a 'substrate-coupled' using 20% (v/v) of 2-propanol as hydrogen donor. Excellent anti-Prelog stereoselectivity was obtained, which is less common found in nature. (c) 2008 Elsevier B.V. All rights reserved.
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