期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 386, 期 -, 页码 114-119出版社
ELSEVIER
DOI: 10.1016/j.molcata.2014.02.001
关键词
Polymer-supported palladium nanoparticles; Alcohol aerobic oxidation; Green chemistry; Recyclable catalyst; Water solvent
资金
- Italian MIUR [2010FPTBSH_001]
This work deals with the catalytic conversion of benzyl alcohols to aldehydes or ketones using a polymer supported palladium catalyst which formed metal nanoparticles under reaction condition. The oxidation reaction was carried out on a series of substituted benzylic alcohols under air in water. The obtained results showed high selectivity also for the oxidation of primary alcohols to aldehydes without over-oxidation products. In addition, the catalyst was recycled several times with negligible metal leaching into solution. (C) 2014 Elsevier B.V. All rights reserved.
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