期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 393, 期 -, 页码 8-17出版社
ELSEVIER
DOI: 10.1016/j.molcata.2014.05.038
关键词
Catalytic epoxidation; Supported complexes; Manganese complexes; H2O2 activation; Activated carbon, D-strain
资金
- European Union (European Regional Development Fund-ERDF)
- Greek national funds (EPAN-II), PEP-Sterea Ellada-Epirus-Thessaly within Action SYNERGASIA
A new synthetic methodology to covalently anchor Mn-II-Schiff-base catalysts onto activated carbon (ACox) has been applied, resulting in heterogeneous Mn-II-L@ACox materials. These catalysts are effective and selective towards epoxides with H2O2, in the presence of CH3COONH4, as co-catalyst, providing TONs equivalent-to/or higher than the homologous Mn-II-L@SiO2 catalysts for certain substrates. Moreover MnII-L@ACox catalysts are re-usable and kinetically faster than the corresponding Mn-II-L@SiO2 catalysts resulting in considerably higher TOFs. Combining catalytic and EPR spectroscopic data we propose a catalytic reaction mechanism which elucidates the co-catalytic function of CH3COONH4 which is of key importance for the successful performance of the studied Mn-II-catalysts. (C) 2014 Elsevier B.V. All rights reserved.
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