期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 330, 期 1-2, 页码 35-40出版社
ELSEVIER
DOI: 10.1016/j.molcata.2010.06.028
关键词
Lewis acid catalyst; Aluminum chloride; Immobilization; Cross-linked polyvinyl alcohol microsphere
资金
- Innovative Experiment Project for College Students in Shanxi Province
Aluminum chloride was covalently bound to cross-linked polyvinyl alcohol (CPVA) microspheres, giving rise to polymer-supported Lewis acid catalysts CPVA-AlCl3 with a high loading (2.07 mmol/g). Their chemical structures were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, atomic absorption spectrometry, and chemical analysis methods. The catalytic activity of CPVA-AlCl3 as well as the relationship between structure and activity was investigated by using Friedel-Crafts acylation reaction of polystyrene. These results suggest that during the immobilization process the structure of the bound aluminum chloride gradually changed from the monomeric form (-AlCl2) to the dimeric form (-Al2Cl5). The presence of -Al2Cl5 gives rise to a catalytic activity enhancement, and the activities of various forms of CPVA-AlCl3 follow an order: CPVA-Al2Cl5 > transitional form > CPVA-AlCl2. In addition, this kind of immobilized Lewis acid catalyst has excellent recyclability and reusability, and in particular, CPVA-Al2Cl5 displayed an extremely low extent of catalyst deactivation in the repeated acylation reactions. (C) 2010 Elsevier B.V. All rights reserved.
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