期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 298, 期 1-2, 页码 31-35出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.molcata.2008.09.027
关键词
Asymmetric transfer hydrogenation; Magnetic nanoparticles; Mesoporous silica; Imine; Ketone
资金
- National Natural Science Foundation of China [20621063, 20423004]
- Program for Strategic Scientific Alliances between China and Netherlands [2004CB720607, 20520130214]
Ru-TsDPEN (TsDPEN=N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine) derived catalyst was firstly immobilized in the magnetic siliceous mesocellular foam material. This heterogeneous catalyst afforded high catalytic activities and ee values in the asymmetric transfer hydrogenation of imine in HCOOH-Et3N system and aromatic ketones in aqueous HCOONa. Furthermore, this heterogeneous catalyst showed an excellent durability and can be reused conveniently by external magnet for at least nine times without noticeable loss of ee values. (C) 2008 Published by Elsevier B.V.
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