期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 298, 期 1-2, 页码 36-39出版社
ELSEVIER
DOI: 10.1016/j.molcata.2008.09.029
关键词
Titanium alkoxide catalyst; Silica support; Polylactide; Ring-opening polymerization
资金
- Korean Government [KRF-2007-331-D00096]
TiCl(O-i-Pr)(3)/SiO2 and Ti(O-i-Pr)(4)/SiO2 were prepared by immobilizing titanium(]V) chloride triisopropoxide (TiCl(O-i-Pr)(3)) and titanium(IV) tetraisopropoxide (Ti(O-i-Pr)(4), respectively, over pretreated silica. A series of solution polymerizations Of L-lactide were conducted with homogeneous alkoxide catalysts and silica-supported titanium alkoxide catalysts to compare their catalytic activity and the characteristics of the polylactide (PLA) produced. The conversion Of L-lactide with the silica-supported alkoxide catalysts was higher than that with homogeneous catalysts even though the catalyst activity was low. In addition, the PLA produced using silica-supported alkoxide catalysts had a higher molecular weight and T than those produced with the homogeneous catalyst. (C) 2008 Elsevier B.V. All rights reserved.
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