期刊
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
卷 291, 期 1-2, 页码 1-4出版社
ELSEVIER
DOI: 10.1016/j.molcata.2008.06.001
关键词
Alcohol oxidation; Selectivity; Ionic liquids; Molecular sieve
A novel combination of catalyst system of CuCl/TEMPO-IL/MS3A, which catalyzed the aerobic oxidation of alcohols in ionic liquid [bmim][PF6] into aldehydes or ketones in high yields and selectivity, was reported. Molecular sieve 3A was found to have a significant beneficial effect on the catalytic reactions. The beneficial effect of Molecular sieve 3A was attributed to its Bronsted base property. With TEMPO being immobilized on ionic liquid to form TEMPO-IL and the use of a heterogeneous promoter of MS3A, the catalyst system could easily be recycled and reused without loss in catalytic activity. (c) 2008 Published by Elsevier B.V.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据