期刊
JOURNAL OF MINING AND METALLURGY SECTION B-METALLURGY
卷 49, 期 1, 页码 77-82出版社
TECHNICAL FACULTY, BOR-SERBIA
DOI: 10.2298/JMMB121101027N
关键词
Electrospinning; Nanofiber; Poly(vinyl alcohol); Zirconium oxide; Zirconium carbide; Zirconium nitride
Poly(vinyl alcohol)-zirconium compound hybrid nanofibers (precursors) were formed by electrospinning employing water as a solvent for the spinning solution. The precursors were converted into oxide (ZrO2), carbide (ZrC) or nitride (ZrN) nanofibers by heating them in air, Ar or N-2 atmospheres. Monoclinic ZrO2 nanofibers with high-specific surface area were obtained by heat-treatment of the precursors in air. ZrC and ZrN nanofibers could be obtained below theoretical temperatures calculated from thermodynamics data.
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