期刊
JOURNAL OF MEMBRANE SCIENCE
卷 455, 期 -, 页码 375-383出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2014.01.003
关键词
Bis(triethoxysilyDethane (BTESE); Silica; Methylcyclohexane; Dehydrogenation; Membrane reactor
High-performance organic-inorganic hybrid silica membranes were developed for use in membrane reactors for methylcyclohexane (MCH) dehydrogenation to toluene (TOL). The membranes were prepared via sol-gel processing using bis(triethoxysilyl)ethane (BTESE). In particular, the effect of hydrolysis conditions (H2O/BTESE molar ratio) on membrane performance was extensively investigated. Characterization based on TO-MASS, FTIR, N-2 adsorption and positron annihilation lifetime (PAL) measurements of BTESE-derived silica gels revealed that the ethoxides of BTESE were almost completely hydrolyzed and the silica networks became dense by increasing the H2O/BTESE molar ratio from 6 to 240. BTESE-derived silica membranes showed a hydrogen permeance that was higher than 1 x 10 mol/ (m(2) s Pa). H-2/TOL selectivity increased from 100 to 10,000 by increasing the H20/BTESE molar ratio from 6 to 240, while keeping a hydrogen permeance of more than 1 x 10(-6) mol/(m(2)s Pa). In MCH dehydrogenation, a BTESE-derived silica membrane reactor with a Pt/gamma-Al2O3/alpha-Al2O3 bimodal catalytic layer achieved MCH conversion of 75% that was higher than the equilibrium conversion of 60%, and a hydrogen purity in the permeate stream of more than 99.9% at 230 degrees C. 2014 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据