期刊
JOURNAL OF MEMBRANE SCIENCE
卷 425, 期 -, 页码 105-112出版社
ELSEVIER
DOI: 10.1016/j.memsci.2012.09.038
关键词
Composite polymer electrolyte; Poly(ethylene oxide) segmented polysulfone copolymer; Plastic crystal; Rechargeable lithium battery
资金
- National Natural Science Foundation of China [21273146]
- Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments [J5NBI201002]
It is a compelling challenge to develop solid polymer electrolyte membranes for rechargeable battery with both high ionic conductivity and superior mechanical performance. In this study, we first prepare a new type of all-solid-state composite polymer electrolyte from lithium bis-trifluoromethanesulphonimide (LiTESI), succinonitrile (SN) and poly(ethylene oxide) segmented polysulfone copolymers (PSF-PEO) with various PEO contents in low molecular weight (Mn = 1500 Da), which are synthesized by condensation polymerization. The optimized composite polymer electrolyte PSF-PE035+LiTESI+SN membrane exhibits a remarkable amorphous state; leading to its ionic conductivity of 1.6 x 10(-4) S cm(-1) at room temperature. Especially, the tensile strength of the PSF-PE035+LiTESI+SN electrolyte membrane is still more than 4.3 MPa at 80 degrees C, indicating its excellent mechanical property and high thermal stability in a wide temperature range. Li symmetric cell and Li/LiFePO4 cell with the above electrolyte display low voltage polarization and good rechargeability. The test results indicate that the solid PSF-PE035+LiTESI+SN composite electrolyte membrane is a promising candidate for future applications in rechargeable lithium batteries. (c) 2012 Elsevier B.V. All rights reserved.
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