期刊
JOURNAL OF MEMBRANE SCIENCE
卷 431, 期 -, 页码 72-78出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2012.11.017
关键词
Gas separation; Silica membrane; Chemical vapor deposition; Pore size control
Membranes have been developed for separation of specific gas from other gas molecules. Tube type ceramic was used for substrate. Silica membranes derived from tetramethoxysilane (TMOS), phenyltrimethoxysilane (PhTMS) and 3-aminopropylmethyldiethoxysilane (APMDES) were synthesized by chemical vapor deposition (CVD) method at 650 degrees C. Permeation experiments with H-2, CO2 and N-2 with ceramic membranes were performed to determine the gas transport characteristics. H-2/N-2 selectivities of TMOS, PhTMS and APMDES derived membranes were decreased by 1265, 633 and 100. And CO2/N-2 selectivities of TMOS, PhTMS and APMDES derived membrane were increased by 3, 5 and 20. It is suggested that whether the intermediate contained living groups has a large effect on the enlargement of the pore size of amorphous silica membranes.
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