期刊
JOURNAL OF MEMBRANE SCIENCE
卷 401, 期 -, 页码 300-305出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2012.02.017
关键词
Proton conductor; Perovskite; Cermet membrane; Hydrogen permeation
资金
- Natural Science Foundation of China [20976098, 21076118]
- Natural Science Foundation of Shandong Prov [Y2008B07]
- Promotive Research Fund for Excellent Young and Middle-aged Scientists of Shandong Province [2010BSB01011]
- National Basic Research Program of China (973 Program) [2007CB209700]
- Royal Academy of Engineering
BaCe0.95Tb0.05O3-delta (BCTb) proton conducting perovskite powders were first synthesized via an EDTA-CA complexing method. Ni-BCTb cermet membranes were then fabricated by pressing a mixture of the BCTb and Ni powders in a weight ratio of 1: 1 at 10 MPa, followed by sintering at 1400 degrees C for 10 h. The properties of the BCTb powders and the Ni-BCTb membranes were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and conductivity measurement using a 4-probe method. The electrical conductivity of the Ni-BCTb membranes approaches to 400 S cm(-1) at room temperature but decreases with increasing temperatures. The maximum hydrogen permeation flux through the asymmetric Ni-BCTb membrane with a 90 mu m separation top layer integrated with a porous substrate has reached up to 0.914 mL (STP) cm(-2) min(-1) at 850 degrees C when using the 50% H-2/N-2 mixture feed and He as the sweep gas, respectively. The surface exchange reaction kinetics takes a controlling effect on the hydrogen permeation through the membrane. The long-term operation test indicates that the Ni-BCTb cermet membranes are not sufficiently stable for hydrogen permeation due to the phase decomposition of the BCTb perovskite. (C) 2012 Elsevier B. V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据