期刊
JOURNAL OF MEMBRANE SCIENCE
卷 383, 期 1-2, 页码 235-240出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.memsci.2011.08.059
关键词
Oxygen permeation membrane; Perovskite; Mixed conductor; Structural stability; Electrical conductivity
资金
- 863 Program of National High Technology Research Development Project of China [2006AA11A189]
- Beijing Municipal Natural Science Foundation [2102031]
- National Nature Science Foundation of China [20973021]
- Outstanding Doctoral Dissertation Guidance Foundation of Beijing [YB20091000802]
BaFe1-xYxO3-delta (x=0-0.2) materials were synthesized by conventional solid-state reaction process for oxygen separation application. The effects of Y-doping on the crystal structure development, electrical conductivity and oxygen permeability were evaluated. Yttrium introduction effectively stabilize the cubic structure of BaFe1-xYxO3-delta. With Y-doping, the oxidation state of Fe ions reduces, resulting in the increase in oxygen vacancy concentration as charge compensation and the decreases in electrical conductivity. Y-doping enhances the structural stability of BaFe1-xYxO3-delta in reducing atmosphere but decreases the oxygen permeability. Both of them are attributed to the strong binding energy of Y-O bond. The cobalt free membrane BaFe0.95Y0.05O3-delta shows good structural stability under reducing atmosphere and acceptable oxygen permeation flux of 0.798 ml (STP) min(-1) cm(-2) at 900 degrees C for 1.1 mm thick membrane, making it a promising candidate for future practical applications. (C) 2011 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据