期刊
JOURNAL OF MEMBRANE SCIENCE
卷 364, 期 1-2, 页码 111-121出版社
ELSEVIER
DOI: 10.1016/j.memsci.2010.08.007
关键词
Chitosan; Polyaniline; Graft copolymer; Pervaporation; Activation energy
资金
- UGC, New Delhi
Chitosan was grafted with polyaniline through oxidative-radical copolymerization using ammonium persulfate as an initiator. The graft material was used to prepare a series of membranes by the variation of aniline ratio. These membranes were characterized by Fourier transform infrared (FTIR) spectroscopy, wide-angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The resulting membranes were tested for their ability to separate water-isopropanol mixtures by pervaporation in the temperature range of 30-50 degrees C. The membrane containing 1:3 grafting ratio exhibited the highest separation selectivity of 2092 with a flux of 1.19 x 10(-2) kg/m(2) h at 30 degrees C for 10 mass% of water in the feed. The total flux and the flux of water are close to each other particularly for the grafted membranes, signifying that these could be used to break the azeotropic point of water-isopropanol mixtures. From the temperature dependency of diffusion and permeation values, the Arrhenius activation parameters were estimated and discussed in terms of membranes efficiency. All the membranes exhibited positive heat of sorption (Delta H-s), giving endothermic contribution. (C) 2010 Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据