Facilitated transport of CO2 in novel PVAm/PVA blend membrane

A defect-free ultra thin PVAm/PVA blend facilitated transport membrane cast on a porous polysulfone (PSf) support was developed and evaluated in this study. The target membrane was prepared from commercial polyvinyl amine (PVAm) and polyvinyl alcohol (PVA). Effects of experimental conditions were investigated for a CO2-N-2 mixed gas. A CO2/N-2 separation factor of up to 174 and a CO2 permeance up to 0.58 m(3)(STP)/(m(2) h bar) were documented. Experimental results suggest that CO2 is being transported according to the facilitated transport mechanism through this membrane. The fixed amino groups in the PVAm matrix function as CO2 carriers to facilitate the transport whereas the PVA adds mechanical strength to the blend by entanglement of the polymeric chains hence creating a supporting network. The good mechanical properties obtained from the blend of PVA with PVAm, enabled an ultra thin selective layer (down to 0.3 mu m) to be formed on PSf support (with MWCO of 50,000), resulted in both high selectivity and permeance. The PVAm/PVA blend membrane also exhibited a good stability during a 400 h test. (C) 2009 Elsevier B.V. All rights reserved.