期刊
JOURNAL OF MATERIALS SCIENCE
卷 46, 期 24, 页码 7793-7798出版社
SPRINGER
DOI: 10.1007/s10853-011-5759-2
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A new series of Eu3+ ions-activated calcium gadolinium tungstate [Ca2Gd2W3O14] phosphors were synthesized by conventional solid-state reaction method. The X-ray diffraction patterns of the powder samples indicate that the Eu3+: Ca2Gd2W3O14 phosphors are of tetragonal structure. The prepared phosphors were well characterized by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDAX), Fourier transform infrared spectroscopy (FTIR), photoluminescence (PL), and mechanoluminescence (ML) spectra. PL spectra of Eu3+: Ca2Gd2W3O14 powder phosphors have shown strong red emission at 615 nm (D-5(0) -> F-7(2)) with an excitation wavelength lambda (exci) = 392 nm (F-7(0) -> L-5(6)). The energy transfer from tungstate groups to europium ions has also reported. Mechanoluminescence studies of Eu3+: Ca2Gd2W3O14 phosphors have also been explained systematically.
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