4.5 Article

Activation of plasmons and polarons in solar control cesium tungsten bronze and reduced tungsten oxide nanoparticles

期刊

JOURNAL OF MATERIALS RESEARCH
卷 27, 期 6, 页码 965-970

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CAMBRIDGE UNIV PRESS
DOI: 10.1557/jmr.2012.25

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  1. Grants-in-Aid for Scientific Research [22310067] Funding Source: KAKEN

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Dispersions of reduced tungsten oxide and tungsten bronze nanoparticles are known to show a remarkable absorption of near-infrared (NIR) light applicable to solar control filters for automotive and architectural windows. Origin of the NIR absorption has been investigated by analyzing dielectric constants of CsxWO3 (x = 0.15, 0.25, and 0.33) and WO2.72, and using Mie scattering theory. The optical analysis and Mie scattering theory analysis indicate that a localized surface plasmon resonance and polarons of localized electrons contribute alongside to the observed NIR absorption at different wavelengths.

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