期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 45, 页码 24075-24080出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm34798a
关键词
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资金
- NRF [2010-0017552]
- Ministry of Education, Science and Technology, Republic of Korea
- National Research Foundation of Korea [2010-0017552] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
We prepared a highly sensitive molecularly imprinted fluorescent sensor by using a CdSe quantum dot (QD) as a signal transducer and a mesoporous silica nanoparticle as an imprinting material. Bisphenol-A (BPA) was chosen as a model template, which is known as an endocrine disruptor. Binding sites were selectively formed between the pores and CdSe QDs were encapsulated in the pores of the mesoporous silica. QD-encapsulated, molecularly imprinted mesoporous silica (QD-MIMS) particles exhibited excellent molecular recognition properties in terms of both sensitivity and selectivity. Owing to the proximity of the binding sites to the QDs, a significant, concentration-sensitive fluorescence quenching was observed in the presence of BPA. QD-MIMS showed a linear Stern-Volmer relationship for BPA and its analogs. QD-MIMS had a much larger quenching constant for BPA (by more than ten times) than for BPA analogs, demonstrating the high selectivity of QD-MIMS.
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