期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 6, 页码 2520-2525出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1jm14199f
关键词
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资金
- National Research Foundation of Korea (NRF)
- Ministry of Education, Science and Technology [2011-0025391]
- Korea Research Council of Fundamental Science and Technology (KRCF)
- Korean Government (MEST) [NRF-C1AAA001-2010-0029065]
- MEST [2009-0093814]
- NRF
In this manuscript, we introduce a facile hydrothermal method for the controlled growth of SnO2 nanoparticles onto graphene oxide. Hydrazine plays a fundamental role in controlling the formation and crystallization of SnO2 nanoparticles, and the reduction of graphene oxide to graphene. The SnO2-graphene composite consists of 3-4 nm monodisperse SnO2 nanocrystals homogeneously dispersed at the surface of graphene. It is demonstrated that the composite can accommodate the large volume change of SnO2 which occurs during lithiation-delithiation cycles. When used as an anode material for lithium ion batteries, it exhibits a first discharge capacity of 1662 mA h g(-1), which rapidly stabilizes and still remains at 626 mA h g(-1) even after 50 cycles, when cycled at a current density of 100 mA g(-1). Even at the very high current density of 3200 mA g(-1), the composite displays a stable capacity of 383 mA h g(-1) after 50 cycles.
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