期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 15, 页码 7314-7322出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm15645h
关键词
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资金
- National Science Council of Taiwan [98-2221-E-006-110-MY3, 101-3113-E-006-010, 101-3113-E-006-011]
- Bureau of Energy, Ministry of Economic Affairs, Taiwan [101-D0204-2]
A novel composite of KOH activated mesophase pitch (aMP) and carbon nanotubes (CNTs) shows outstanding performance as an electrode for electric double-layer formation in 2 M H2SO4. The aMP powder is highly porous and the KOH activation may produce pores that are populated with graphitic edges. The resulting aMP electrode has a capacitance value of 295 F g(-1) at 0.125 A g(-1) discharge and decreases to 180 F g(-1) at 100 A g(-1). With particle milling, the pore diffusion resistance of the aMP electrode decreases significantly because of the elimination of a hindered diffusion mode from the particle interior. CNT addition provides inter-particle spacing and bridging media for the milled aMP and reduces the Warburg diffusion and electrical resistance. The composite of milled aMP and CNTs has capacitance values of 305 F g(-1) at 0.125 A g(-1) and 214 F g(-1) at 100 A g(-1). With a small potential window of 1 V, the resulting symmetric cells can deliver an energy level of 8.2 Wh kg(-1) at a high power of 10 000 W kg(-1). These cells show superior stability, with no decay of specific capacitance after 10 000 cycles of galvanostatic charge and discharge.
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