期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 9, 页码 3745-3751出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm15662h
关键词
-
资金
- THERMOSPIN [ANR-10-NANO-012-02]
- PRES-Universite de Toulouse
The investigation of size-reduction effects on the spin crossover properties of a class of transition metal complexes has recently become an area of intensive research. However, to avoid inter-particle interactions, ensemble averaging and matrix effects it is necessary to develop methods for the systematic study of individual nano-objects. To this aim thin films and nano-patterns of the compound [Fe-II(hptrz)(3)](OTs)(2) doped with acridine orange were elaborated by spin coating and soft-lithography, respectively. The luminescence intensity was found to change significantly upon the spin transition even in isolated nano-objects of ca. 150 nm size, allowing us to monitor in a massively parallel way the spin crossover phenomenon in large arrays via fluorescence microscopy.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据