期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 48, 页码 25174-25182出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm35148j
关键词
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资金
- Australian Research Council (ARC) [DP098753]
In order to exploit the inherent properties of carbon nanotubes (CNT) in any polymer composite, systematic control of carbon nanotube loading and protocols that mitigate against CNT bundling are required. If such composites are to be rendered in fiber form via wet-spinning, then CNT bundling during the coagulation process must also be avoided. Here we have achieved this by utilizing highly exfoliated single walled carbon nanotubes (SWNT) and poly(3,4-ethylenedioxythiophene): poly(styrenesulfonicacid) (PEDOT:PSS) to obtain wet-spinnable composite formulations at various nanotube volume fractions (V-f). The addition of only 0.02 V-f of aggregate-free and individually dispersed SWNT resulted in a significant enhancement of modulus, tensile strength, electrical conductivity and two cell electrode specific capacitance of PEDOT:PSS-SWNT composite fibers to 5.2 GPa, 200 MPa, 450 S cm(-1) and 59 F g(-1) by the rate of dY/dV(f) = 89 GPa, d sigma/dV(f) = 3.2 GPa, dS/dV(f) = 13 300 S cm(-1) and 6 folds, respectively.
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