期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 44, 页码 23587-23592出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm35263j
关键词
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资金
- National Natural Science Foundation of China [21176101, 20771045, 20676052]
- Natural Science Foundation of Zhejiang Province [Y4080404]
- countries 12th Five-Year Plan to support science and technology project [2011BAK10B03]
- Qing Lan Project
Nickel-cobalt double hydroxide microspheres (Ni-Co-DHM) have been synthesized by a facile and cost-effective in situ method. The obtained Ni-Co-DHM displays a three-dimensional architecture with hollow interior and hedgehog-like exterior structures. The unique architecture greatly improves the faradaic redox reaction and mass transfer. The Ni-Co-DHM electrode offers an excellent pseudocapacitance performance, including high specific capacitance and rate capability, good charge-discharge stability and long-term cycling life. Its maximum specific capacitance was found to be 2275.5 F g(-1) at current density of 1 A g(-1), which is more than 3-fold that of common nickel-cobalt double hydroxides and 2-fold that of the mechanical mixture of Co(OH)(2) and Ni(OH)(2) microspheres. The specific capacitance can remain at 1007.8 F g(-1) when the current density increases to 25 A g(-1). The capacitance can keep at least 92.9% at current density of 10 A g(-1) after 5000 cycles. Therefore, this work provides a promising approach for the design and synthesis of structure tunable materials with largely enhanced supercapacitor behavior, which can be potentially applied in energy storage/conversion devices.
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