4.3 Article

Three-dimensional ordered macroporous IrO2 as electrocatalyst for oxygen evolution reaction in acidic medium

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JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 13, 页码 6010-6016

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm16506f

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资金

  1. National Natural Science Foundation of China [20973131, 21073137]
  2. National Basic Research Program of China [2012CB932800]
  3. Fundamental Research Funds for the Central Universities

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Three-dimensional ordered macroporous (3-DOM) IrO2 was synthesized by using the silica colloidal crystal template method and explored as electrocatalyst for oxygen evolution reaction (OER) in acidic medium. X-Ray diffraction (XRD) patterns indicate that the prepared 3-DOM IrO2 has a rutile structure. Images of scanning and transmission electron microscopies suggest that the 3-DOM IrO2 possesses a hierarchical pore structure, in which the honeycomb array of 300 nm primary macropores were cross-linked by secondary mesopores on the walls. The presence of mesopores is also indicated by the N-2 adsorption/desorption isotherms and the small-angle XRD patterns. As compared with IrO2 prepared by conventional colloidal method, the 3-DOM IrO2 exhibited much larger BET area and voltammetric charges. Accordingly, about two and half times enhancement in OER activity was achieved by using 3-DOM IrO2 as the electrode materials, showing prospect of 3-DOM materials in reducing the demand of the expensive IrO2 electrocatalyst for OER in water electrolysis.

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