期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 12, 页码 5382-5389出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm15928g
关键词
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资金
- NSFC/China [61006048]
- Fundamental Research Funds for the Central Universities [WJ1014025]
- National Basic Research 973 Program [2011CB808400]
- Scientific Committee of Shanghai [10520709700]
- NSFC [20902027, 91027005]
- Shanghai Pujiang Program [09PJ1404100]
- Shanghai Shuguang Program [09SG25]
- SMEC [10ZZ32]
- Fundamental Research Funds for the Central Universities
A new family of linear structure Pt(II) (triphenylamine alkynyl) 2(triethyl-phosphine) (2-carboxy-2-cyanovinyl-X-alkynyl) (where X thiophene (PT1), [2, 2']-bi-thiophene (PT2) or 1,2-di(2-thienyl) ethylene) (PT3)) complexes have been synthesized and characterized. The introduction of thiophene pi-bridges enhanced the extent of electron delocalization over the whole molecules, so their maximum absorption peaks were red shifted. These complexes have been tested as dye-sensitized solar cell (DSSC) sensitizers. PT2 showed the best photovoltaic performance, yielding 4.21% power conversion efficiency using a volatile electrolyte. As shown in an electrochemical impedance experiment, the different charge transfer resistance (R-ct) of the three sensitizers influences their injection lifetime of electrons and then their photoelectrical properties.
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