4.3 Article

Preparation of carbon coated MoO2 nanobelts and their high performance as anode materials for lithium ion batteries

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JOURNAL OF MATERIALS CHEMISTRY
卷 22, 期 26, 页码 13148-13152

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ROYAL SOC CHEMISTRY
DOI: 10.1039/c2jm31364b

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  1. MOST Programs [2010DFA61770]
  2. NSFC [21073046]

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Carbon coated MoO2 nanobelts were successfully synthesized via a hydrothermal method followed by calcination under inert atmosphere, using alpha-MoO3 nanobelts as the precursor and self-template, ethanol as the reducer and glucose as the carbon source. Under the protection of polysaccharide resulting from glucose polycondensation, the 1-D morphology can be well retained during the reduction and carbonization processes. Tested as anode materials for lithium ion batteries, the carbon coated MoO2 nanobelts exhibit a reversible capacity of 769.3 mA h g(-1) at a current density of 100 mA g(-1) in the first cycle, and retain 80.2% of the capacity after 30 cycles. When the current density increases, this material shows high rate capability and good cycling performance.

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